期刊
EUROPEAN POLYMER JOURNAL
卷 72, 期 -, 页码 23-33出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2015.08.033
关键词
Electro-hydrodynamic processing; Phase change materials; Superchilling; Temperature buffers
资金
- EU
- MINECO [MAT2012-38947-C02-01]
- Ministry of Higher Education, Science, Technology and Innovation (SENESCYT) from Ecuador
- Spanish Ministry of Economy and Competitivity
In this work, a PCM with a phase transition temperature set at 1.5 degrees C was encapsulated inside polycaprolactone (PCL), polystyrene (PS) and high-impact polystyrene (HIPS) matrices by means of electro-hydrodynamic processing in order to develop thermal energy storage systems for food superchilling applications. Different solvents were screened to prepare the electrospinning solutions which were seen to directly affect the properties of the obtained structures in terms of morphology, heat storage capacity, supercooling degree and thermal behavior. As a strategy to improve the heat management properties of the developed hybrid structures, solvents with different physicochemical properties (dielectric constant, viscosity and solubility, among others) were mixed in optimized ratios. Aside from more homogeneous electrospun fiber morphologies, the use of polymer solutions prepared with solvent mixtures resulted in improved thermal properties of the hybrid heat management materials, which showed melting and crystallization temperatures and a supercooling degree similar to that obtained for the pure PCM. The best encapsulation efficiency was achieved for PCL-based hybrid structures, which showed that similar to 92 wt.% of the incorporated PCM, effectively remained within the polymeric matrix. (C) 2015 Published by Elsevier Ltd.
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