期刊
NANOMATERIALS
卷 7, 期 8, 页码 -出版社
MDPI AG
DOI: 10.3390/nano7080228
关键词
prussian blue; electrode material; mesostructure; supercapacitor
类别
资金
- National Natural Science Foundation of China [51772249, 51402236, 51472204]
- State Key Laboratory of Solidification Processing (NWPU), China [123-QZ-2015]
- Key Laboratory of New Ceramic and Fine Processing
- State Key Laboratory of Control and Simulation of Power System and Generation Equipment (Tsinghua University) [KF201607, SKLD17KM02]
- Fundamental Research Funds for the Central Universities
Mesoporous cobalt hexacyanoferrate nanocubes (meso-CoHCF) were prepared for the first time through a facile sacrificial template method. The CoHCF mesostructures possess a high specific surface area of 548.5 m(2).g(-1) and a large amount of mesopores, which enable fast mass transport of electrolyte and abundant energy storage sites. When evaluated as supercapacitor materials, the meso-CoHCF materials exhibit a high specific capacitance of 285 F.g(-1), good rate capability and long cycle life with capacitance retention of 92.9% after 3000 cycles in Na2SO4 aqueous electrolyte. The excellent electrochemical properties demonstrate the rational preparation of mesoporous prussian blue and its analogues for energy storage applications.
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