期刊
MACROHETEROCYCLES
卷 10, 期 2, 页码 134-146出版社
IVANOVO STATE UNIV CHEMICAL TECHNOLOGY
DOI: 10.6060/mhc170512a
关键词
Thiacalix[4]arene; synthetic methods; amphiphile; molecular recognition
资金
- Russian Science Foundation [14-13-01151]
- Ministry of Education and Science of Russian Federation
- Russian Science Foundation [17-13-00040] Funding Source: Russian Science Foundation
A consolidated review on the synthesis of lower rim tetrasubstituted thiacalixarenes and their self-assembly on the soft surfaces contributed from our group is presented. The approaches for the synthesis of different types of tetra-O-substituted thiacalixarenes from the last 10 years are discussed. In addition, amphiphilic macrocycles in 1,3-alternate conformation form monolayers at the interface and are effectively embedded into the vesicles. Decorated by thiacalixarenes nanolayers and vesicles demonstrate a high selectivity towards specific analytes.
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