期刊
ENERGY TECHNOLOGY
卷 5, 期 11, 页码 1908-1911出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201700108
关键词
carbon cloth; electrochemistry; cobalt nickel nitride; hydrogen evolution; water splitting
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Waterloo
- Waterloo Institute for Nanotechnology
The design and synthesis of electrocatalysts possessing both hydrogen and oxygen evolution activity is of critical importance to simplify the water splitting system. In this work, we reported the preparation of porous Ni-Co nitride nanowires (NiCoN NWs) supported on carbon cloth, and used as bifunctional electrocatalysts to achieve overall water splitting. Benefiting from the 1D porous nanowire structure, the close contact between catalysts and support, and the increased conductivity, the resultant NiCoN NWs exhibited high activities in both the hydrogen and oxygen evolution reactions (HER and OER) with low overpotential at a current density of 10 mA cm(-2) (approximate to 145 mV for HER and 360 mV for OER), low Tafel slope (105.2 mV dec(-1) for HER and 46.9 mV dec(-1) for OER), and good electrochemical stability. Good stability was also obtained upon using the material as HER and OER catalysts in a two-electrode system to split water.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据