期刊
CHEMELECTROCHEM
卷 4, 期 10, 页码 2442-2447出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201700627
关键词
metal-organic frameworks; oxygen reduction; nitrogen-doped graphene aerogel; Fe3O4; porous materials
资金
- National Key Research and Development Program of China [2017YFA0206701]
- National Program for Support of Top-notch Young Professionals
- Changjiang Scholar Program
A novel Fe3O4 nanoparticles/nitrogen-doped graphene aerogel (denoted as Fe3O4@NGA) hybrid material with high porosity was prepared by using iron-based metal-organic frameworks (MOFs), [Fe3O(H2N-BDC)(3)] (H2N-BDC=2-aminoterephtalic acid), denoted as MIL-88B-NH2, as templates and nitrogen-doped graphene aerogel (NGA) as the substrate. The obtained Fe3O4 nanoparticles demonstrate a rich edge area with abundant exposed active sites and defects, indicating great potential for oxygen adsorption and activation. When used as an electrocatalyst in alkaline solution, the Pt-free Fe3O4@NGA exhibited excellent oxygen reduction reaction (ORR) performance and dramatically enhanced durability and tolerance towards methanol compared to commercial Pt/C catalyst, revealing its great viability and potential in practical application.
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