期刊
CATALYSTS
卷 7, 期 8, 页码 -出版社
MDPI AG
DOI: 10.3390/catal7080228
关键词
ionic liquid; beta-hydroxy carboxylic acids; [Bmim][Co(CO)(4)]; carbonylation; water
资金
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015M3D3A1A01064879]
- National Research Foundation of Korea [2015M3D3A1A01064879] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The reported catalytic system demonstrates the possibility of efficient mass production of 3-hydroxybutyric acid (3-HBA) from inexpensive raw materials. The direct coupling of propylene oxide, water, and CO was catalyzed by 1-butyl-3-methylimidazolium cobalt tetracarbonyl ([Bmim][Co(CO)(4)]) ionic liquid to form 3-HBA with >99% conversion (49% selectivity) under mild conditions.
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