期刊
CATALYSTS
卷 7, 期 3, 页码 -出版社
MDPI AG
DOI: 10.3390/catal7030092
关键词
biomass; 5-hydroxymethylfurfural; 2,5-bis-(hydroxymethyl) furan; catalytic transfer hydrogenation; ruthenium based catalyst
资金
- China Scholarship Council [201508330154]
- Natural Science Foundation of Zhejiang province [LY17C160008]
- National Natural Science Foundation of China [21406208]
- China Postdoctoral Science Foundation funded project [2014M560532]
- open Foundation of the Most Important Subjects in Colleges and Universities in Zhejiang Province [2015YXQN13]
- Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci.-Tech. University [YR2015005]
- 521 Talent Cultivation Program of Zhejiang Sci.- Tech. University [11110132521309]
- open fund of the Key Laboratory of Pulp and Paper Science & Technology of the Ministry of Education of China [KF201411]
2,5-Bis-(hydroxymethyl) furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hydrogenation (CTH) process, using isopropanol as the hydrogen source and Ru/Co3O4 as the catalyst, was studied. The results revealed that the Ru/Co3O4 catalyst displayed a high catalytic efficiency, and that a BHMF yield of up to 82% was obtained at 190 degrees C in 6 h. Moreover, it was found that the recovered Ru/Co3O4 exhibited a similar catalytic activity to the pristine Ru/Co3O4 catalyst. These results supported the conclusion that the present CTH process is an attractive green route for the synthesis of BHMF from biomass-based HMF.
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