期刊
CATALYSTS
卷 7, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/catal7070218
关键词
carbohydrates; furanic derivatives; choline chloride; low melting mixture; deep eutectic solvent
资金
- ANR agency [NR-15-CE07-0016]
The synthesis of furanic derivatives (5-hydroxymethylfurfural (HMF), furfural...) from carbohydrates is of high interest for a wide range of applications. These reactions are carried out in the presence of various solvents, and among them choline chloride can be used. It is a salt that can form a low melting mixture with a carbohydrate (fructose, glucose . . . ) or a deep eutectic mixture with carboxylic acid. A review of the studies performed in the conversion of carbohydrates to furanic derivatives in the presence of choline chloride is presented here with the advantages and drawbacks of this solvent. Choline chloride can enhance the selectivity to HMF by stabilizing effect and allows the conversion of highly concentrated feed. However, the extraction of the products from these solvents still needs improvement.
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