4.8 Article

Mg vacancy and dislocation strains as strong phonon scatterers in Mg2Si1-xSbx thermoelectric materials

期刊

NANO ENERGY
卷 34, 期 -, 页码 428-436

出版社

ELSEVIER
DOI: 10.1016/j.nanoen.2017.03.012

关键词

Magnesium silicide; Thermoelectric materials; Thermal conductivity; Dislocation; Magnesium vacancy

资金

  1. National Basic Research Program of China [2013CB632503]
  2. Nature Science Foundation of China [11574267, 51571177, 61534001]

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Mg2Si based solid solutions have unique advantages in the direct thermal to electrical energy conversion due to environmentally friendly and abundant constituent elements, and high thermoelectric performance. Further enhancing figure of merit zT of this materials system lies in the reduction of the relatively high lattice thermal conductivity. Alloying by high content of aliovalent Sb (> 10%) in Mg2Si can greatly suppress the lattice thermal conductivity, lower than conventional Mg-2(Si, Sn) solid solutions, due to the enhanced phonon scattering from Mg vacancy and concomitant strains. In this work, detailed microstructure observation for Sb alloyed Mg2Si reveal the existence of dense dislocations, around which the strip-like defects are viewed with isotropic strain. By introducing dislocations and vacancies as the additional phonon scattering sources, the model calculation can well match the experimental lattice thermal conductivity. The present work offers a comprehensive understanding of the role of vacancies and concomitant strains in reducing thermal conductivity, and may open a new venue for zT enhancement.

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