期刊
NANO ENERGY
卷 41, 期 -, 页码 327-336出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2017.09.045
关键词
Bifunctional; Overall water splitting; Hierarchical; Core-shell; Cu@CoFe LDH
类别
资金
- National Natural Science Foundation of China [21377044, 21573085]
- US Department of Energy [DE-SC0010831]
- China Scholarship Council
Efficient and low-cost bifunctional catalysts toward both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) for overall water splitting are of great significance to energy and environmental sustainability. Here, we report on a novel hierarchical Cu@CoFe layered double hydroxide (LDH) core-shell nanostructure catalyst for efficient overall water splitting in the alkaline medium. Benefiting from the smart structure, the optimized composite affords small overpotentials of 171 mV for the HER and 240 mV for the OER at a current density of 10 mA cm(-2), along with Tafel slopes of 36.4 and 44.4 mV dec(-1) for the HER and OER, respectively. Strikingly, the overall water splitting performance is very good since it just requires a voltage of 1.681 V to gain a current density of 10 mA cm(-2), which is only 60 mV larger than the benchmark of IrO2 (+)/Pt (-) electrodes. Moreover, the optimized composite electrodes exhibit outstanding durability within 48 h testing, which is much better than that of the benchmark. Our rational design of the hierarchical core-shell nanoarchitectures presents a simple approach to fabricate advanced catalysts for water splitting.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据