期刊
NANO ENERGY
卷 42, 期 -, 页码 341-352出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2017.11.030
关键词
Hierarchical hollow micro-polyhedrons; Bi-component ZnO/ZnFe2O4; Nitrogen-doped carbon matrix; Metal-organic frameworks; Lithium-ion batteries; In situ XRD diffraction
类别
资金
- Chinese Scholarship Council (CSC)
- Helmholtz Association
In this work, a facile and potentially scalable self-template synthesis of bi-component ZnO/ZnFe2O4/N-doped C micro-polyhedrons with hierarchical hollow structure (ZZFO-C) is presented. These are obtained through calcination of a single bi-metallic metal-organic framework (MOF) precursor (ZIF-ZnFe, molar ratio of 3: 1). The resulting material shows a high surface area and is constituted by the organized assembly of numerous nanoparticles sub-unit (with size in the range of 20 nm). By tuning the annealing conditions, porous ZnO/ZnFe2O4 (ZZFO) micro-polyhedrons are obtained. The ZZFO-C composite materials are studied as anodes for LIBs exhibiting remarkable energy storage performance, such as, large reversible capacity (ca. 1000 mA h g(-1) after 100 cycles at 200 mA g(-1)), excellent rate capability and cycling stability. After high-rate capacity testing (1000 cycles at 2.0 A g(-1)), ZZFO-C shows an excellent reversible capacity of 620 mA h g(-1). The excellent performance of ZZFO-C arises from its unique hierarchical hollow structure and the synergy between the two active components and the N-doped carbon matrix. The electrochemical reaction mechanism and structure phase changes upon the initial lithiation are identified via in situ X-ray diffraction studies.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据