期刊
NANO ENERGY
卷 42, 期 -, 页码 166-172出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2017.10.052
关键词
Ni-Fe battery; Aqueous electrolyte; Iron anode; Iron oxide; Nanocrystal; Molecular confinement
类别
资金
- Institute for Materials Science and Devices, Suzhou University of Science and Technology (USTS)
- Thousand Young Talents Plan [D1211038]
- USTS [331712107]
- National Natural Science Foundation of China [21375108, 21605110, B050206]
Nickel-iron (Ni-Fe) rechargeable batteries are attractive as sustainable solutions for large-scale electrical energy storage because of their low cost, eco-friendliness and safety, but their iron anodes always suffer from low capacity and poor stability, which greatly limits their wide applications. We present here a molecular confinement strategy to fabricate ultrasmall iron oxide nanocrystals firmly mounted on carbon (mc-FeOx/C) that works as stable anode material for high energy density Ni-Fe batteries. Compared with conventional iron oxide on carbon synthesized without molecular confinement (FeOx/C), the mc-FeOx/C exhibits a much higher capacity (370.2 vs 159.5 mAh g(-1) at a current density of 2 A g(-1)) and better stability (capacity retention of 93.5% vs 61.2% after 1000 charge/discharge cycles). When to further combine with a nickel cathode, the mc-FeOx/C based Ni-Fe battery delivers an energy density up to 173.7 Wh kg(-1), among the highest value for Ni-Fe batteries reported so far. The mc-FeOx/C based Ni-Fe battery also offers excellent rate capability (e.g., 112.6 Wh kg(-1) at 28.9 kW kg(-1)) and good stability (capacity retention of 91.6% after 1000 cycles), retaining their applications for large-scale electrical energy storage.
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