期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 201, 期 -, 页码 310-317出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2016.08.017
关键词
H-2 energy; Gold catalysts; Copper-Zinc catalysts; Hydrotalcite precursor; WGS
资金
- Spanish Ministerio de Educacion y Competitividad (MEC) - FEDER funds from the European Union [ENE2012-374301-C03-01, ENE2013-47880-C3-2-R]
- Junta de Andalucia [TEP-8196]
- Spanish Ministerio de Economia y Competitividad [BES-2014-068244]
Outstanding catalysts for the water was shift reaction are reported in this work. The combination of gold nanoparticles with Cu/ZnO/Al2O3 prepared from hydrotalcite-like precursors leads to very promising systems for pure hydrogen production. Full CO conversion is reached at temperatures as low as 180 degrees C. The key point seems to be the cooperation of Au and Cu and the optimal metal-oxide contact derived from the synthesis method. The high activity of gold for low temperature CO oxidation and the suitability of copper for the WGS results in a perfect synergy. Moreover the materials developed in this work present good stability and tolerance towards start/stop cycles an indispensable requisite for a realistic application in an integrated hydrogen fuel processor. (C) 2016 Elsevier B.V. All rights reserved.
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