期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 9, 页码 4325-4330出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta00220c
关键词
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资金
- MEXT program Elements Strategy Initiative to Form Core Research Center MEXT
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- JSPS KAKENHI Grant [JP16K14103]
- Grants-in-Aid for Scientific Research [16K14103] Funding Source: KAKEN
Recently, research on novel and low cost batteries has been widely conducted to realize large-scale energy storage systems. However, few of the battery systems have delivered performance equal to that of Li-ion batteries. Herein, we propose non-aqueous K-ion batteries by developing hexacyanoferrate(II) compounds (so-called Prussian blue analogues), K1.75Mn[FeII(CN)(6)] (0.93)center dot 0.16H(2)O and K1.64Fe[FeII(CN)(6)](0.89)center dot 0.15H(2)O, as affordable positive electrode materials. In particular, K1.75Mn [FeII(CN)(6)](0.93)center dot 0.16H(2)O prepared by a simple precipitation process delivers a high capacity of 141 mA h g(-1) at 3.8 V as the average operating potential, resulting in a comparable energy density to that of LiCoO2, with excellent cyclability and rate performance in K halfcells. Operando X-ray diffraction measurements reveal that the excellent electrochemical performance of this material is attributed to its open and flexible framework, which can realize fully reversible K+ extraction/insertion and a structural change from monoclinic to tetragonal via cubic phases. For the first time, we demonstrate an inexpensive high-voltage K-ion full cell with a K1.75Mn[Fe(CN)(6)](0.93)center dot 0.16H(2)O/graphite configuration to prove its feasibility as a new promising battery system for an environmentally friendly future.
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