期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 39, 页码 20843-20850出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta06679a
关键词
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资金
- Ministry of Science and Technology (MOST) of Taiwan [104-2221-E-001-014-MY3, 104-2221-E-009-096-MY3]
- Career Development Award of Academia Sinica, Taiwan [103-CDA-M01]
- Hong Kong Polytechnic University [1-ZE29]
Organic-inorganic lead halide perovskites have recently emerged as highly competitive light absorbing materials for low cost solution-processable photovoltaic devices. With the high efficiency already achieved, removing the toxicity, i.e., lead-free and stability are the key obstacles for perovskite solar cells. Here, we report the synthesis of an antimony (Sb)-based hybrid material having the composition of A(3)Sb(2)I(9) [A = CH3NH3 (MA), Cs] and an investigation of its potential photovoltaic applications. Sb-based perovskite-like materials exhibited attractive absorbance properties, with the band gaps of MA(3)Sb(2)I(9) and Cs3Sb2I9 measured to be 1.95 and 2.0 eV, respectively. X-ray photoelectron spectroscopy confirmed the formation of stoichiometric perovskites from appropriate precursor molar ratios incorporated with hydroiodic acid (HI). Planar hybrid Sb-based solar cells exhibited negligible hysteresis and reproducible power output under working conditions. A power conversion efficiency of 2.04% was achieved by the MA(3)Sb(2)I(9) perovskite-based device-the highest reported to date for a Sb-based perovskite solar cell.
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