期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 17, 页码 7744-7748出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta01907f
关键词
-
资金
- National Natural Science Foundation of China [21603215, 21435005, 21627808]
- Key Research Program of Frontier Sciences, Chinese Academy of Sciences [QYZDY-SSW-SLH019]
The execution of the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) requires active, low-cost, and earthabundant electrocatalysts to realize large-scale water splitting. Herein, by utilization of the electrodeposition technique, a new category of nickel-based materials, i.e. nanoporous nickel hydroxide@nickel (Ni(OH)(2)@Ni) films on carbon cloth (Ni(OH)(2)@ Ni/CC), has been reported as a Janus electrocatalyst for overall water splitting. The asdeposited Ni(OH)(2)@ Ni/CC exhibited remarkable catalytic performance for the HER in alkaline electrolytes with an overpotential of 68 mV needed to drive the current density of 10 mA cm(-2) and much better durability than Pt/C. This film is also efficient for catalyzing the OER in basic media. These films can be employed as catalysts on both the anode and cathode for overall water splitting that approaches 10 mA cm(-2) at a cell voltage of 1.58 V, with catalytic stability exceeding those with RuO2 and Pt/C catalysts. Density functional theory calculations further demonstrate that the Ni(OH)(2) and Ni in Ni(OH)(2)@Ni films synergistically favor the chemisorption of hydrogen-containing intermediates, thus leading to highly enhanced water splitting activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据