4.6 Article

Graphene highly scattered in porous carbon nanofibers: a binder-free and high-performance anode for sodium-ion batteries

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 4, 页码 1698-1705

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta09961k

关键词

-

资金

  1. NSF of China [51532002, 51372022, 51575030, 51622102, 51231003, 51571124]
  2. 973 Project [2015CB932500]
  3. National Postdoctoral Program for Innovative Talents [BX201600014]
  4. China Postdoctoral Science Foundation [2016M600042]

向作者/读者索取更多资源

Graphene monolayers or bilayers highly scattered in porous carbon nanofibers (denoted as G/C) are first prepared by a feasible electrospinning technique. Meanwhile, G/C with the character of a flexible membrane adherent on copper foil is directly used as binder-free anode for Na-ion batteries, exhibiting fascinating electrochemical performance in terms of high reversible capacity (432.3 mA h g(-1) at 100 mA g(-1)), exceptional rate capability (261.1 mA h g(-1) even at 10 000 mA g(-1)), and ultra-long cycling life (91% capacity retention after 1000 cycles). This is due to the synergistic effect between the highly exfoliated graphene layers and the porous carbon nanofibers, which can provide massive active Na-storage sites, ensure sufficient electrolyte infiltration, offer open ionic diffusion channels and oriented electronic transfer pathways, and prevent graphene agglomeration as well as carbon nanofiber fracture upon prolonged cycling. The findings shed new insights into the quest for high-performance carbon-based anode materials of sodium-ion batteries.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据