期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 22, 页码 10866-10875出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta01499f
关键词
-
资金
- National Natural Science Foundation of China [51673047]
Oil contamination is problematic in subaqueous environments. It is difficult to prepare long-lasting textured superhydrophilic/underwater oil-repellent coatings without using a sophisticated method. Here, an ultra-facile and low-cost immersion-curing approach has been developed to generate superhydrophilic and underwater superoleophobic coatings from poly(vinyl alcohol) (PVA)/silica (SiO2) nanocomposites. During immersion curing, polymeric dissolution occurs simultaneously with crosslinking but occurs solely at the topmost layer, and helps to create enriched hierarchical surface micro-/nanostructures. Hence, superhydrophilicity is attainable for nanocomposite coatings with a filler percentage of only 15 wt%. Immersion-cured PVA/SiO2 nanocomposite coatings with 35 wt% silica have an excellent underwater superoleophobicity in terms of durability and ultra-low oil adhesion towards a variety of oils, including viscous crude oil. Because of its lower filler content and confined porous structure, this coating has a greater transparency compared with its conventional blend-curing underwater superoleophobic counterpart. Immersion-cured nanocomposite coatings display an excellent mechanical durability based on pencil hardness (3H) and sand-abrasion performance. The extra acrylic/melamine base-coat allows the underwater superoleophobic PVA/SiO2 coatings to be applied to diverse substrates, including glass, metals, and plastics, and renders them free from oil in aqueous environments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据