4.6 Article

Nanocarbon-intercalated and Fe-N-codoped graphene as a highly active noble-metal-free bifunctional electrocatalyst for oxygen reduction and evolution

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 5, 页码 1930-1934

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta09232a

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资金

  1. National Basic Research Program of China [2012CB215504]
  2. NSFC [51372186, 21273214, 21425521, 21521001]
  3. Hefei Center for Physical Science and Technology [2014FXCX010]
  4. Collaborative Innovation Center of Suzhou Nano Science and Technology
  5. Royal Society for a Newton International Fellow
  6. China Postdoctoral Science Foundation [2014M551811]
  7. State Key Laboratory of Advanced Technology for Material Synthesis and Processing (Wuhan University of Technology) [2014KF- 9]
  8. Fundamental Research Funds for the Central Universities

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We report a rationally designed electrocatalyst with high activity for both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) based on a nanocarbon-intercalated graphene (CIG) material doped with nitrogen (N) and iron (Fe) (Fe-N-CIG). This easily made novel 3D Fe-N-CIG catalyst exhibits a surprisingly high ORR and OER activity and stability, making it a new noble-metal-free bifunctional catalyst for future applications in regenerative energy conversion systems.

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