期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 39, 页码 20631-20634出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta07440a
关键词
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资金
- National Natural Science Foundation of China [21573068]
- Program of Shanghai Subject Chief Scientist [15XD1501300]
- Fundamental Research Funds for the Central University [222201718002, 222201714001]
- National Postdoctoral Program for Innovative Talents [BX201600050]
- Shanghai Sailing Program [17YF1402900]
- Shanghai Municipal Education Commission
- Shanghai Education Development Foundation [16CG31]
- China Postdoctoral Science Foundation [2016M601523]
Here, for the first time, we detect reversible structural changes of platinum oxide as an active site in photocatalytic water splitting by operando X-ray absorption fine structure spectroscopy. The platinum-oxygen bond length increases from 2.07 to 2.13 angstrom A and the coordination number reduces from 4.0 to 2.5 between the ex situ and operating photocatalysts.
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