期刊
ARKIVOC
卷 -, 期 -, 页码 557-578出版社
ARKAT USA INC
DOI: 10.24820/ark.5550190.p009.829
关键词
Chiral sulfoxides; optically active thioamides; self-disproportionation of enantiomers (SDE); homochiral and heterochiral molecular associations; non-linear effects; achiral column chromatography; enantiomeric enrichment and depletion
资金
- IKERBASQUE, Basque Foundation for Science
- Ministry of Science and Higher Education [612 561]
- National Science Center (Krakow, Poland) [UMO 2014/15/B/ST5/05329]
This review presents a comprehensive, critical treatment of all the literature data related to the phenomenon of the SDE taking place during gravity-driven achiral chromatography of scalemic compounds bearing sulfoxide and thioamide functionalities. The discussion is focused on the SDE magnitude as a function of the structure iof the compound, composition of eluent and stationary phase, including some mechanistic details. An apparent possibility of application of the SDE phenomenon via achiral chromatography as a novel, emerging unconventional enantiomeric purification technique is also discussed. [GRAPHICS] .
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