期刊
BIOSENSORS & BIOELECTRONICS
卷 87, 期 -, 页码 888-893出版社
ELSEVIER ADVANCED TECHNOLOGY
DOI: 10.1016/j.bios.2016.09.053
关键词
Cu2+; Catalytic reaction; AuNPs; SERS; RRS
类别
资金
- National Natural Science Foundation of China [21367005, 21465006, 21477025, 21567001, 21567005, 21667006]
- Natural Science Foundation of Guangxi [2013GXNSFFA019003]
With development of economy and society, there is an urgent need to develop convenient and sensitive methods for detection of Cu2+ pollution in water. In this article, a simple and sensitive SERS sensor was proposed to quantitative analysis of trace Cu2+ in water. The SERS sensor platform was prepared a common gold nanoparticle (AuNP)-SiO2 sol substrate platform by adsorbing HSA, coupling with the catalytic reaction of Cu2+-ascorbic acid (H(2)A)-dissolved oxygen, and using label-free Victoria blue B (VBB) as SEAS molecular probes. The SERS sensor platform response to the AuNP aggregations by hydroxyl radicals (center dot OH) oxidizing from the Cu2+ catalytic reaction, which caused the SERS signal enhancement. Therefore, by monitoring the increase of SERS signal, Cu2+ in water can be determined accurately. The results show that the SERS sensor platforms owns a linear response with a range from 0.025 to 25 mu mol/L Cu2+, and with a detection limit of 0.008 mu mol/L. In addition, the SERS method demonstrated good specificity for Cu2+, which can determined accurately trace Cu2+ in water samples, and good recovery and accuracy are obtained for the water samples. With its high selectivity and good accuracy, the sensitive SERS quantitative analysis method is expected to be a promising candidate for determining copper ions in environmental monitoring and food safety.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据