期刊
CERAMICS INTERNATIONAL
卷 43, 期 1, 页码 157-161出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2016.09.127
关键词
Amine-functionalization; Precursor; Colloidal alumina; Ceramic core; Infiltration
资金
- National Research Foundation of Korea (NRF) - Korea government [2014R1A2A1A11050220]
- Power Generation and Electricity Delivery of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Ministry of Trade, Industry and Energy, Korea [20142020103400]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20142020103400] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2014R1A2A1A11050220] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The surface characteristics of nano-sized alumina particles were modified to include amine functional groups to enhance the infiltration behavior in a silica-based ceramic core, inhibiting crystallization of the cristobalite phase in order to improve mechanical properties. In this study, polymer-based polyethylenimine (PEI) or silane-based (3-Aminopropyl)triethoxysilane (APTES) were used as precursors in amine group addition. The specimens were characterized by the C-H stretching vibration and N-H bending vibration or the symmetric stretching vibration of siloxane group (Si-O-Si) in the FT-IR spectra, depending on the nature of the molecular structure of the precursor molecule. The dispersion properties were also improved through electrostatic repulsion or steric hindrance. These modifications resulted in a PEI-grafted colloidal alumina particle that induced a more rapid infiltration process with greater efficiency than did the APTES-treated particle. The rapid infiltration of the ceramic core suppressed the formation of the cristobalite phase, improved the flexural strength from 3.2 to 10.2 MPa, and reduced the linear shrinkage rate from 1.91-1.05%.
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