Gas dependent sensing mechanism in ZnO nanobelt sensor

Gas sensing properties of ZnO nanobelts synthesized using carbothermal reduction method has been investigated. At room temperature (28 degrees C), the sensor films exhibit an appreciable response towards H2S and NO and response of these two gases were studied as a function of concentration. For NO the sensor films exhibit a complete reversible curve for the concentration range between 1 and 60 ppm. However, for H2S a complete recovery was obtained for concentration <5 ppm and for higher concentration a partial recovery of the baseline resistance was observed. The reason for the incomplete recovery was investigated using X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) studies of the sample before and after the H2S exposure. After exposure, appearance of an additional peak at 26.6 degrees corresponding to the formation of ZnS was observed in XRD. Formation of additional phase was further corroborated using the results of XPS. H2S exposure causes decrease in the intensity of O 1s peak and appearance of sulphide peaks at binding energies of 162.8 and 161.8 eV corresponding to S-2p peaks -2p(3/2) and 2p(1/2), confirms the formation of ZnS upon exposure. (C) 2016 Elsevier B.V. All rights reserved.