Structural and optical properties of sol gel derived Cu2ZnSnS4 nanoparticles

The spherical Cu2ZnSnS4 nanoparticles with the average diameters (similar to 8-10 nm) have been synthesized by sol gel method. The effects of solvents and reaction temperatures on the properties of the as-synthesized nanoparticles were investigated. The X-ray diffraction shows as grown Cu2ZnSnS4 nanoparticles exhibit kesterite crystal structure along preferential orientation (112) plane. The crystalline nature of nanoparticles was improved in ethylene glycol solvent with the increase in reaction temperature. Rietveld refinement study was performed and structural parameters were determined for the Cu2ZnSnS4 nanoparticles. The Raman spectra show the main characteristic peak of A(1) vibrational mode which confirmed the formation of Cu2ZnSnS4 phase in all the samples. Scanning electron micrographs depict the irregular aggregate formation of nanoparticles in methanol solvent and uniformly distributed aggregates of nanoparticles with ethylene glycol solvent. Transmission electron microscopy results show the synthesis of polycrystalline porous nanostructures and uniform spherical nanoparticles in methanol and ethylene glycol solvents respectively at the temperature of 250 degrees C. UV-vis absorption spectra indicated the broad absorption in visible range and the band gap of the nanoparticles was found to 1.38 and 1.45 eV which is suitable for absorbing the solar radiation. The obtained results revealed ethylene glycol as a suitable solvent and 250 degrees C as the favorable synthesis temperature. (C) 2016 The Society of Powder Technology Japan.