期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 9, 页码 2026-2030出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201605776
关键词
condensation; cycloaddition; cyclocarbonylation; lactones; oxidation
资金
- National Natural Science Foundation of China [21672244, 21532002, 21372248]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20020200]
Two monocyclic members in the gracilioether family were synthesized in only three steps. The monocyclic products were further elaborated into advanced precursors to hippolachnin A and gracilioether E, respectively. Gracilioether F and the alleged structure for gracilioether I were also synthesized using a late-stage C(sp(3))-H thermo-oxidation.
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