期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 10, 页码 2439-2447出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201605043
关键词
addition-elimination; beta-fragmentation; multicomponent reactions; radicals
资金
- CNRS
- MNERT
- ANR [RAD-MCRN811-BS07-010-01]
- Grants-in-Aid for Scientific Research [15F15410] Funding Source: KAKEN
The three-component free-radical carbo-alkenylation of electron-rich olefins has been studied, varying the substitution pattern in the alkene, in the radical precursor and in the final acceptor. New vinylsulfones were also prepared and their reactivity investigated. The scope and limitations of the process was established, and the reaction mechanism clarified using selected dienes as radical clocks. It was thus recognised that the reversible addition onto the olefin of the released sulfonyl group is an important event, which should not be overlooked when using such multicomponent carbo-alkenylation reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据