期刊
ARKIVOC
卷 -, 期 -, 页码 303-312出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.p009.826
关键词
Selenium; electrophile; cyclization; tetrahydrofurans; alkenols
In this manuscript the kinetic resolution of 2-methoxycarbonylalk-3-enols is reported through a stereoselective selenocyclization promoted by an electrophilic sulfur-containing selenium reagent. Reacting one equivalent of the selenenenylating agent with two equivalents of racemic starting material afforded a mixture of a stereoselectively enriched tetrahydrofuran and the corresponding enantiomerically enriched alkenols. [GRAPHICS] .
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