期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 7, 页码 1704-1718出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201609372
关键词
asymmetric synthesis; natural products; schinortriterpenoids; total synthesis
资金
- National Science Foundation [CHE-1363105]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1363105] Funding Source: National Science Foundation
Since the pioneering days of total synthesis and retrosynthetic analysis, the community has embraced guiding principles for planning synthetic approaches towards complex natural products. These guideposts have enabled the community to synthesize ever more complex compounds by applying prior knowledge gained in new settings. The recently isolated schinortriterpenoid family of natural products has attracted considerable synthetic attention and provided a rich opportunity to evaluate the lessons learned in the construction of complex, polycyclic scaffolds. In this Minireview, a detailed discussion of the synthetic work within this family is provided, including the six reported total syntheses, as well as a comparative analysis of the approaches utilized in their construction.
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