期刊
ANALYTICAL CHEMISTRY
卷 89, 期 3, 页码 1900-1906出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.6b04377
关键词
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资金
- Natural Science Foundation of China [21275023, 11532003, 21476031]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center [ACGM2016-06-24]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Construction of convenient systems for isomer discrimination is of great importance for medical and life sciences. Here, we report a simple and effective chiral sensing device based on a highly ordered self-assembly framework. Cu2+-modified beta-cyclodextrin (Cu-beta-CD) was self-assembled to the ammonia-ethanol cotreated chitosan (ae-CS), and the highly ordered framework was gradually formed during the re-growth process of the shrinked ae-CS films. Tryptophan (Trp) isomers were well discriminated with the highly ordered framework by electrochemical approach. This study is the first example showing how an ordered structure influences chiral recognition.
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