期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 8, 页码 2045-2049出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611595
关键词
C-H activation; fluorine; meta-selectivity; phosphine; ruthenium
资金
- European Research Council under European Community/ERC [307535]
- CSC
Ruthenium(II)-catalyzed meta-selective C-H (di) fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C-H functionalization was characterized by ample substrate scope, thereby setting the stage for meta-(di) fluoromethylation through facile C-H cleavage.
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