期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 8, 页码 2101-2104出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610901
关键词
hydrogen bonds; molecular crystals; organic frameworks; porous materials; thermal stability
资金
- 973 Program [2014CB932101, 2013CB933200]
- Strategic Priority Research Program of the CAS [XDB20000000]
- Chunmiao Project of Haixi Institutes [CMZX-2016-001]
A robust hydrogen-bonded organic framework HOF-TCBP (H4TCBP=3,3',5,5'-tetrakis-(4-carboxyphenyl)-1,1'-biphenyl) has been successfully constructed and structurally characterized. It possesses a permanent 3D porous structure with a 5-fold interpenetrated dia topological network. This activated HOF-TCBP has a high BET surface area of 2066 m(2) g(-1) and is capable of highly selective adsorption and separation of light hydrocarbons under ambient conditions. It shows excellent thermal stability, as demonstrated by PXRD experiments and N-2 adsorption tests. Practical use of HOF-TCBP is facilitated by the ease of its preparation and renewal through rotary evaporation.
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