期刊
COORDINATION CHEMISTRY REVIEWS
卷 333, 期 -, 页码 1-26出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2016.11.009
关键词
Interlocked; Metallasupramolecules; Coordination-driven assembly; Supramolecular chemistry
资金
- National Science Foundation of China [21531002, 21374019]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT-15R12]
- Shanghai Science Technology Committee [13JC1400600, 16ZD2270100]
Interlocked molecules are a type of supramolecules whose sub-components are held together not by covalent bonds but non-covalent interactions. Examples include rotaxanes, catenanes, Solomon links, ring-in-ring complexes, molecular Borromean rings, molecular knots and interlocked cages. The design and manufacture of these architectures is mainly based on self-assembly and template-directed methodologies. Inspired by the successful utilization of coordination-driven assembly in metallasupramolecular systems, the metallacyclic assembly of interlocked superstructures is developing rapidly and as such makes a fascinating topic for reviewing. In this review we will focus on the metal-directed synthesis of the different types of interlocked superstructures, as well as their functional applications. (C) 2016 Elsevier B.V. All rights reserved.
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