期刊
ACTA MATERIALIA
卷 125, 期 -, 页码 481-489出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2016.12.021
关键词
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资金
- National Natural Science Foundation of China [51531001, 51671018, 51422101, 51371003, 51271212]
- 111 Project [B07003]
- International SAMP
- T Cooperation Program of China [2015DFG52600]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_14R05]
- Fundamental Research Fund for the Central Universities [FRF-TP-15-004C1]
- Top Notch Young Talents Program
- Scientific User Facilities Division, Office of Basic Energy Sciences, United States Department of Energy
- US Department of Energy (DOE) [DE-AC05-00OR22725]
In this paper, we report the development of rare-earth high-entropy alloys (RE-HEA) with multiple principle elements randomly distributed on a single hexagonal close-packed (HCP) lattice. Our work demonstrated that it is the entropy, rather than other atomic factors such as enthalpy, atomic size and electronegativity, that dictates phase formation in the current rare-earth alloy system. The high configuration entropy stabilized the crystalline structure from phase transformation during cooling, whereas a second-order magnetic phase transition occurred at its Neel temperature. The quinary RE-HEA exhibited a small magnetic hysteresis and the largest refrigerant capacity (about 627 J kg(-1) at the 5 T magnetic field) reported to date, along with respectable mechanical properties. Our analysis indicates that the strong chemical disorder resulted from the high configuration entropy makes magnetic ordering in the HEA difficult, thus giving rise to a sluggish magnetic phase transition and enhanced magneto caloric effect. Our findings evidenced that RE-HEAs have great potential to be used as magnetic refrigerants and the alloy-design concept of HEAs can be employed to develop novel high-performance magnetocaloric materials. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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