期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 14, 页码 2283-2286出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09824j
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资金
- U.S. Department of Energy, Basic Energy Sciences, Materials Sciences Division [DE-SC0012582]
- Texas A&M University Vice President of Research
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1310574] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-SC0012582] Funding Source: U.S. Department of Energy (DOE)
A pair of related dinuclear lanthanide compounds, viz., [Dy(tmhd)(3)](2)(bptz) (1) and {Cp2Co}{[Dy(tmhd)(3)](2)(bptz)} (2) (tmhd = 2,2,6,6-tetramethyl-3,5-heptane dionate; bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine) are reported. These molecules represent the first study of rare earth ions in which an organic ligand bridged species is isolated in both the neutral and radical anion forms. Both compounds exhibit out-of-phase signals below 4 K. The radical compound is highly air stable, with minimal changes in magnetic behavior after exposure to the atmosphere for two weeks.
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