期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 9, 页码 2482-2486出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611974
关键词
borylation; carboxylic acids; decarbonylation; rhodium catalysts; thioesters
资金
- JSPS KAKENHI [15K05509]
- Special Postdoctoral Researcher Program from RIKEN
- Grants-in-Aid for Scientific Research [15K05509] Funding Source: KAKEN
Transformation of aromatic thioesters into aryl-boronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
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