Tuning the stability of bimetallic Ce(IV)/Zr(IV)-based MOFs with UiO-66 and MOF-808 structures

A series of solid solutions of bimetallic Ce/Zr-UiO-66 and -MOF-808 compounds with a varying ratio of Ce4+ to Zr4+ were obtained under mild reaction conditions within 15 min. The lattice parameters of the mixed-metal compounds are in accordance with Vegard's law. Samples with Ce <= 20 at% exhibit an enhanced thermal stability, better resistance against acids and smaller particle sizes.