A convenient electrolytic assembly of graphene-MOF composite thin film and its photoanodic application

In the recent past, the metal organic frameworks (MOFs) have been recognized as attractive photosensitizer materials due to their hierarchically ordered structures and attractive light-harvesting characteristics. In this work, we report the application of a graphene-MOF composite as a potential photosensitizer material in dye-sensitized solar cells (DSSCs). A thin film of graphene-MOF hybrid composite was electrochemically assembled on a TiO2/FTO substrate and the different characteristics of the prepared film were investigated. This novel photoanode material hybrid structure demonstrated the potency of an alternative solid-state DSSC configuration. The 2.2% observed power conversion efficiency of the above graphene-MOF composite is a good basis for the further development of graphene-MOF composite-based photoanodes. (C) 2016 Elsevier B.V. All rights reserved.