期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 8, 页码 6967-6978出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b11498
关键词
iron carbide; iron oxide; cobalt-nickel sulfide; supercapacitor; pulse electrodeposition; alkaline rechargeable battery
资金
- Department of Chemistry, Mississippi State University
Nanostructured nickel cobalt sulfide (Ni4.5Co4.5S8) has been prepared through a single-step pulse-electrodeposition method. Iron oxide nanosheets at hollow graphite shells (Fe3O4@g-shells) were prepared from graphite-coated iron carbide/alpha-Fe (g-Fe3C/Fe) in a two-step annealing/electrochemical cycling process. Electrochemical characterization of the Ni4.6Co4.6S8 and g-Fe3C/Fe materials showed that both have high specific capacities (206 mAh g(-1) and 147 mAh g(-1) at 1 A g(-1)) and excellent rate capabilities (similar to,95% and similar to 83% retention at 20 A g(-1), respectively). To demonstrate the advantageous pairing of these high rate materials, a full-cell battery with supercapacitor-like power behavior was assembled with Ni4.6Co4.6S8 and g-Fe3C/Fe as the positive and negative electrodes, respectively. The (Ni4.5Co4.6S8//g-Fe3C/Fe) device could be reversibly operated in a 0.0-1.6 V potential window, delivering an impressive specific energy of 89 Wh kg(-1) at 1.1 kW kg(-1) and a remarkable rate performance of 61 Wh kg(-1) at a very high specific power of 38.5 kW kg(-1). Additionally, long-term cycling demonstrated that the asymmetric full cell assembly retained 91% of its initial specific capacity after 2500 cycles at 40 A g(-1). The performance features of this device are among the best for iron oxide/hydroxide and bimetallic sulfide based energy storage devices to date, thereby giving insight into design principles for the next generation high-energy-density devices.
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