期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 8, 页码 7465-7471出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b16034
关键词
one-pot; 3D graphene nanocomposites; peroxidase mimics; colorimetry; glucose detection
资金
- National Natural Science Foundation of China [21375123, 21675151]
- Ministry of Science and Technology of China [2013YQ170585, 2016YFA0203201]
A novel one-pot strategy is proposed to fabricate 3D porous graphene (3D GN) decorated with Fe3O4 nano particles (Fe3O4 NPs) by using hemin as iron source. During the process, graphene oxide was simultaneously reduced and self assembled to form 3D graphene hydrogel while Fe3O4. NPs synthesized from hemin distributed uniformly on 3D GN. The preparation process is simple, facile, economical, and green. The obtained freeze-dried product (3D GH-5) exhibits outstanding peroxidase-like activity. Compared to the traditional 2D graphene-based nanocomposites, the introduced 3D porous structure dramatically improved the catalytic activity, as well as the catalysis velocity and its affinity for substrate. The high catalytic activity could be ascribed to the formation of Fe3O4 NPs and 3D porous graphene structures. Based on its peroxidase-like activity, 3D GH-5 was used for colorimetric determination of glucose with a low detection limit of 0.8 mu M.
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