期刊
CERAMICS INTERNATIONAL
卷 43, 期 3, 页码 2962-2968出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2016.11.048
关键词
Tellurite glasses; Niobium; Zinc; Hydroxyl groups; Transparency; Raman; Immiscible liquids
资金
- Japan Society fo the Promotion of Science (JSPS) International Training Program (ITP), Young Scientist-Training Program for World Ceramics Networks
- Institute of Ceramics Research and Education (ICRE), Nagoya Institute of Technology
Low-hydroxyl (OH)-content, transparent zinc-niobate-tellurite glasses (TeO2-Nb2O5-ZnO and TeO2-Nb2O5-ZnCl2) were synthesized by using dry-air atmospheres, stirring of the melt, and preheat treatment before melt preparation. A low OH level (79.8 +/- 6.3 ppm) was achieved by performing a preheat treatment of mixed raw chemicals with zinc chloride and then melting in both open-and dry-air atmospheres with several counts of intermittent stirring. However, this sequence of processes resulted mainly in non-crystallized, opaque products. The basis of this opacity was investigated by performing Raman spectroscopy, X-ray diffraction (XRD), and Xray fluorescence (XRF) measurements on both the opaque and transparent glasses. Raman spectroscopy revealed that the proportion of Te-O-Te bonds, relative to tellurite unit structures (TeO4, TeO3+1, and TeO3), in the opaque glasses decreased with increasing isolated structures of TeO32-. This decrease resulted possibly from atomic-scaled inhomogeneity and immiscible domain formation in the melts and corresponding glasses, which have less amounts of residual OH groups.
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