期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 11, 页码 3080-3084出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201612486
关键词
cobalt; dehydrogenation; heterocycles; photochemistry; reaction mechanisms
资金
- NSFC [21472145]
- Fundamental Research Funds for the Central Universities [xjj2015099]
Herein, the first acceptorless dehydrogenation of tetrahydroquinolines (THQs), indolines, and other related N-heterocycles, by merging visible-light photoredox catalysis and cobalt catalysis at ambient temperature, is described. The potential applications to organic transformations and hydrogen-storage materials are demonstrated. Primary mechanistic investigations indicate that the catalytic cycle occurs predominantly by an oxidative quenching pathway.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据