期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 3, 页码 278-282出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601313
关键词
homogeneous catalysis; hydroacylation; nickel; reaction mechanisms; transition metals
资金
- JSPS KAKENHI [16KT0057, JP15H00943, JP15H05803]
- Scientific Research on Innovative Areas Stimuli-responsive Chemical Species [2408]
- Frontier Research Base for Global Young Researchers, Osaka University, on the program of MEXT
- JSPS
- Grants-in-Aid for Scientific Research [16KT0057, 15H05803, 15H00943, 25708018] Funding Source: KAKEN
A combined kinetic and theoretical study was conducted in order to clarify the details on the reaction mechanism for Ni-0/ItBu-catalyzed intramolecular alkene hydroacylation. The results confirm the hypothesis that this intramolecular hydroacylation proceeds through an oxanickelacycle key intermediate.
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