Seawater storage and element transfer associated with mantle serpentinization in magma-poor rifted margins: A quantitative approach

Continental breakup in magma-poor rifted margins can develop, in some instances, after the formation of a wide exhumed domain that can be several hundreds of km wide. As exhumation of the continental mantle occurs serpentinization, due to seawater circulation, can extend as far down as 5-6 km, as observed in refraction seismic data. The impact caused by the process of serpentinization within the evolving ocean may have the potential to change: (i) seawater chemistry; (ii) sustain the evolution of primitive life; (iii) control depositional environments; and (iv) form weak zones preferentially used during the formation, reactivation and subduction of distal rifted margins. Based on geological observations, and geophysical and geochemical data from present-day and fossil zones of exhumed continental mantle, we present a first-order quantification showing that approximately 0.380 km(3) of water per km(2) can be stored in the mantle. Using simple methods, it can be shown that serpentinization may account for a significant loss of Si, Mg, Fe, Mn, Ca, Ni and Cr during serpentinization of mantle rocks. In particular during latest stages of rifting, when basins are often restricted and seaways are not yet connected, exhumation and the serpentinization of large areas of continental mantle may result in a major transfer of elements between the main Earth reservoirs, such as the mantle and seawater. (C) 2016 Elsevier B.V. All rights reserved.