期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 12, 页码 3168-3171出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611623
关键词
boron catalysis; hydrosilylation; rearrangement; silanes; siloxanes
资金
- Ministry of Economy, Trade and Industry, Japan (METI)
- New Energy and Industrial Technology Development Organization (NEDO)
Siloxane bonds are usually synthesized by condensation reactions, such as hydrolysis/dehydration and cross-coupling reactions, in which the generation of by-products during bond formation can not be avoided. We have developed a one-pot sequence of iridium-catalyzed silyl ester hydrosilylation and boron-catalyzed rearrangement of the resulting disilyl acetals for the construction of siloxane bonds, in principle without the formation of any by-products. Moreover, the programmed synthesis of tri-, tetra-, and pentasiloxanes was possible in a single flask by combining the above sequence of iridium-catalyzed hydrosilylation and boron-catalyzed rearrangement with a boron-catalyzed cross-coupling reaction. The obtained oligosiloxanes are difficult to synthesize selectively by other known synthetic procedures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据