期刊
ELECTROCHIMICA ACTA
卷 231, 期 -, 页码 36-43出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.02.037
关键词
alpha-Fe2O3 nanotubes; MnO2 nanosheets; core-shell heterostructures; electrospinning; supercapacitors
资金
- National Natural Science Foundation of China [21474043, 51473065, 51273075, 21274052]
- Graduate Innovation Fund of Jilin University [2015011]
The incompetency of conventional single-phase electrode materials remains a stumbling block for making further breakthroughs in high-performance supercapacitors. In this work, alpha-Fe2O3 nanotube@MnO2 nanosheet hierarchical networks with tunable mass ratio of MnO2 to alpha-Fe2O3 are prepared via a simple two-step method for supercapacitor electrodes. The alpha-Fe2O3@ MnO2 core-shell heterostructures, especially the FM10020 containing 60.1 wt% of MnO2, exhibit a larger specific capacitance of 289.9 F g(-1) at 1.0 A g(-1), a better rate capability of 40.8% at 5.0 A g(-1) and a higher cycling stability of 85.3% after 1200 cycles than the pure MnO2, highlighting the advantages of such unique configuration accompanied by the synergistic effect. It is believed that these intriguing results will provide an alternative way for the construction of metal oxide-based composite nanostructures with improved electrochemical performance. (C) 2017 Elsevier Ltd. All rights reserved.
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