期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 6, 期 3, 页码 335-341出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201600536
关键词
alkenes; hydride ligands; isomerization; organometallic complexes; palladium
资金
- KRICT [SI1504, SI1605]
New stable palladium-hydride complexes catalyze the highly regio- and stereoselective isomerization of 1-alkenes at multiple positions. Tuning the ligand and the reaction conditions allowed the position and geometry of the double bonds to be controlled with excellent conversions and selectivities. The catalytic species, a Pd-H complex, was prepared by reacting [LPdCl2] with a silver salt, followed by conversion into Pd-H by using a silyl hydride. The structures of the Pd complexes were determined by using X-ray crystal-lography and NMR spectroscopy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据