期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 6, 期 11, 页码 1594-1597出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201700367
关键词
cycloaddition; frondosin; natural products; oxidopyrylium; total synthesis
资金
- Marine Biotechnology Program - Ministry of Land, Transport and Maritime Affairs of Korea
An enantio-and stereoselective formal total synthesis of (+)-frondosin A was accomplished through an oxidopyrylium-ion-mediated [5+2] cycloaddition reaction. The cycloaddition reaction provided not only an efficient way of constructing the frondosin skeleton but also facial discrimination through an ether bridge for complete control of relative stereochemistry of the substituents in frondosin A.
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