4.8 Article

B(C6F5)3-Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes

期刊

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 14, 页码 4028-4032

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700864

关键词

boron; carbocations; C C activation; isomerization; strained molecules

资金

  1. National Natural Science Foundation of China [21602114]
  2. 1000-Talent Youth Program
  3. Nankai University

向作者/读者索取更多资源

Catalytic amounts of B(C6F5)(3) promote the ring opening and subsequent isomerization of a series of unactivated cyclopropanes to afford terminal olefins in good yields when a hydrosilane and 2,6-dibromopyridine are employed as additives.

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