期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 10, 页码 1696-1699出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10035j
关键词
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资金
- National Natural Science Foundation of China [21302134]
- Natural Science Foundation of Jiangsu [BK20130338]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
A redox-neutral, mild, and simple protocol is developed for the synthesis of a-trifluoromethylated ketones from vinyl azides under transition-metal-free conditions. In the presence of organic photoredox catalyst N-methyl-9-mesityl acridinium and sodium trifluoromethanesulfinate, a broad range of substituted vinyl azides were found to react smoothly upon visible-light irradiation, readily furnishing the corresponding products in satisfied yields.
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